Significant Research Contributions of
Professor Rama Kant
Chronoapmerometry with Single Potential
Step on Rough Electrodes
Theories
for Charge Transfer, Ohmic, Quasireversibility, Bulk Reaction
1. Facile
(Nernstian) Charge Transfer
Anomalous Cottrellian
Response
Equation
for anomalous diffusion flux on random electrode
Equation for anomalous diffusion
flux on self-affine fractal electrode
Further reading
R. Kant, S. K. Jha, J. Phys. Chem. C,
(Letter) 2007, 111, 14040.
R. Kant, J. Phys. Chem.
B , 1997, 101,3781.
R. Kant, J. Phys. Chem.
, 1994, 98,1663.
R.
Kant, S.K.Rangarajan, J. Electroanal. Chem. C, 1994, 368, 1.
R. Kant, Phys. Rev.
Lett. , 1993,70,4094.
2. Facile (Nernstian) Charge Transfer with Ohmic Corrections
Anomalous Cottrellian Current with Solution Resistance Corrections
Equation
for potentiostatic current transient on random electrode
Graph with random electrode roughness model
3. Quasi-reversible Charge Transfer
Theory of partial
diffusion-limited interfacial transfer/reaction
on realistic fractals
Equation for partial
diffusion-limited
current on self-affine fractal electrode
Further reading
S. K. Jha, R. Kant, J. Electoanal. Chem. 2010, 641, 78.
R.
Kant, S.K.Rangarajan, J. Electroanal. Chem. 1995, 396, 285.
4.
Quasi-reversible Charge
Transfer with Ohmic Corrections
Effect of uncompensated solution resistance on
quasireversible charge transfer at rough and finite fractal electrode
Further reading
S. Srivastav and R. Kant,
J. Phys. Chem. C, 2010, 114, 10066.
R. Kant, M.
Sarathbabu, Shruti Srivastav, Electrochimica Acta, 56 (2011)4467.
5. Facile
Charge Transfer Coupled to Bulk Reaction
Theory of Potentiostatic
Current Transients for
Coupled Catalytic
Reaction at Rough Electrode
Generalized Danckwerts Equation for Coupled Catalytic Reaction at Rough Electrode
Further reading
S. K. Jha, R. Kant, Electrochimica
Acta, 55
(2010) 7266-7275
P. Delahay, G.L. Stiehl, J. Am. Chem. Soc. 74 (1952)
3500.
J. Koutecky, Collect. Czech. Commun. 18 (1953) 597.
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